NIOSH Pocket Guide to Chemical Hazards

Diphenyl CAS 92-52-4
C6H5C6H5 RTECS DU8050000
Synonyms & Trade Names
Biphenyl, Phenyl benzene
DOT ID & Guide
Exposure
Limits
NIOSH REL: TWA 1 mg/m3 (0.2 ppm)
OSHA PEL: TWA 1 mg/m3 (0.2 ppm)
IDLH 100 mg/m3 Conversion 1 ppm = 6.31 mg/m3
Physical Description
Colorless to pale-yellow solid with a pleasant, characteristic odor. [fungicide]
MW: 154.2
BP: 489°F
MLT: 156°F
Sol: Insoluble
VP: 0.005 mmHg
IP: 7.95 eV

Sp.Gr: 1.04
Fl.P: 235°F
UEL(311°F): 5.8%
LEL(232°F): 0.6%

Combustible Solid
Incompatibilities & Reactivities
Oxidizers
Measurement Methods
NIOSH 2530; OSHA PV2022
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: Daily
Provide: Eyewash (molten), Quick drench (molten)
First Aid (See procedures)
Eye: Irrigate immediately
Skin: Water flush immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH/OSHA
Up to 10 mg/m3: (APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s) in combination with a dust and mist filter/(APF = 10) Any supplied-air respirator
Up to 25 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*/(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s) in combination with a dust and mist filter*
Up to 50 mg/m3: (APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter/(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having a high-efficiency particulate filter/(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter*/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Up to 100 mg/m3: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms Irritation eyes, throat; headache, nausea, lassitude (weakness, exhaustion), numb limbs; liver damage
Target Organs Eyes, respiratory system, liver, central nervous system
See also: INTRODUCTION